From 3ab8faeb27f00c045f8e307b27d1ff3c17cf7307 Mon Sep 17 00:00:00 2001 From: Andrew Lorimer Date: Thu, 14 Mar 2019 17:58:29 +1100 Subject: [PATCH] [chem] activation energy, kinetic energy, catalysts --- chem/graphics/catalyst-graph.png | Bin 0 -> 71604 bytes chem/graphics/endothermic-profile.png | Bin 0 -> 51243 bytes chem/graphics/exothermic-profile.png | Bin 0 -> 51128 bytes chem/graphics/ke-temperature.png | Bin 0 -> 55038 bytes chem/reactions.md | 34 ++++++++++++++++++++++++++ 5 files changed, 34 insertions(+) create mode 100644 chem/graphics/catalyst-graph.png create mode 100644 chem/graphics/endothermic-profile.png create mode 100644 chem/graphics/exothermic-profile.png create mode 100644 chem/graphics/ke-temperature.png create mode 100644 chem/reactions.md diff --git a/chem/graphics/catalyst-graph.png b/chem/graphics/catalyst-graph.png new file mode 100644 index 0000000000000000000000000000000000000000..7675cbecdfc57f0ee63d75c5d6f0694ee5802611 GIT binary patch literal 71604 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zojP?II&>&SLjL(ns*JhKh2w^8+O(k%`@#z^Hu5o>RJ*6kq8dq0W`&a6fy6f^!1Vo@P0tyNXf0ssI2 literal 0 HcmV?d00001 diff --git a/chem/reactions.md b/chem/reactions.md new file mode 100644 index 0000000..92df05f --- /dev/null +++ b/chem/reactions.md @@ -0,0 +1,34 @@ +# Rates and Equilibria + +## Energy profile diagrams + +$$E_A = E_{\text{max}} - E_{\text{initial}}$$ + +- Energy always needed to initiate reaction (break bonds of reactants) +- Reactant particles must collide at correct angle, energy etc +- Most collisions are not fruitful + +![](graphics/endothermic-profile.png) +![](graphics/exothermic-profile.png) + +**Ways to increase rate of reaction:** + +1. Increase surface area +2. Increase concentration/pressure +3. Increase temperature + +## Kinetic energy + +Temperature - measure of _avg_ kinetic energy of particles. Over time each particle will eventually have enough energy to overcome $E_A$. +Note same distribution indicates same temperature. +![](graphics/ke-temperature.png) + +## Catalysts + +- alternate reaction pathway, with lower $E_A$ +- increased rate of reaction +- involved in reaction but regenerated at end + +**Homogenous** catalyst: same state as reactants and products, e.g. Cl* radicals. +**Hetrogenous** catalyst: different state, easily separated. Preferred for manufacturing. +![](graphics/catalyst-graph.png) -- 2.43.2