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groups) + \item Soluble in other non-polar solvents e.g. fats, oils + \item Can be synthesised endogenously + \end{itemize} + + \subsection*{Water-soluble vitamins} + + \begin{itemize} + \item Absorbed directly into bloodstream + \item Catalyse cellular reactions + \item Excreted through kidneys in urine + \item Must be obtained from food + \end{itemize} + + \section{Proteins} + + \begin{itemize} + \item All proteins contain C, H, O, N + \item Plants make proteins from inorganic compounds, animals cannot + \item Built from monomers called \textbf{amino acids} + \end{itemize} + + \subsection*{Aminio acids} + + \begin{itemize} + \item Contains amino (\ce{-NH2}) and carboxyl (\ce{-COOH}) + \item Most have four groups bonded to central atom + \item May be polar or non-polar (amphoteric), acidic or basic + \item \textbf{Essential amino acids} - cannot be synthesised, must be supplied in diet + \item Amino acids (except glycine) are enantiomers due to chiral centres + \item Must be correct chirality to act as a biological catalyst + \end{itemize} + + % amino acid general structure (see Jacaranda p.328) + + \chemfig{\color{red}N(-[:135]H)(-[:225]H)-[:-45]C(-[:-90]\color{yellow}\textit{R})(-H)-[:45]\color{blue}C(=[:90]O)-OH} + + \subsection*{Zwitterions} + + \begin{itemize} + \item Zwitterion = \textit{dipolar ion} + \item Behaves as a base in acidic environments: \ce{-COOH- + H+ -> -COOH} + \item Behaves as an acid in basic environments: ammonium group loses \ce{H+} \(\implies\) anionic form + \end{itemize} + + % Zwitterion structural equation (Jacaranda p.330) + + \[ \ce{$\underset{\text{acid form}}{\ce{^+H3N-CH2-COOH}}$ <=>[+H+] $\underset{\text{zwitterion form}}{\ce{^+H3N-CH2-COO-}}$ <=>[-H+] $\underset{\text{basic form}}{\ce{H2N-CH2-COO-}}$} \] + \[ \text{cationic} \hspace{12cm} \text{anionic} \] + + \subsection*{Formation of proteins} + + \[ \text{Amino acid} \rightarrow \text{peptide} \tag{polymerisation} \] + + Peptide group (amide): \ce{-C=ONH} (condensation reaction produces \ce{H2O}) + + Amino acid \textit{residue} - product of peptide formation reaction + + Large polypeptides are called \textit{proteins} + + \subsection*{Protein structure} + + \begin{enumerate} + \item \textbf{Primary structure} - order of amino acids in peptide chain + \item \textbf{Secondary structure} - coils/pleats/folds in polymer + \item \textbf{Tertiary structure} - three-dimensional structure, e.g. H-bonding, ionic bonding + \item \textbf{Quaternary structure} - arrangement of multiple protein molecules + \end{enumerate} + + % diagram of structural levels (Jacaranda p.332) + + \subsection*{Enzymes} + + \begin{itemize} + \item Biological catalysts (lowers \(E_A\)) + \item Names usually end in \textit{-ase} + \item Every enzyme has a unique 3D shape + \item Rate of reaction \(\propto\) concentration up to \textit{saturation point} + \item \textbf{Substrate} - reactant molecule + \item \textbf{Active site} - destination of substrate + \end{itemize} + + % enzyme catalyst diagram (Jacaranda p.334) + + \subsubsection*{Lock and key model} + + Reactants and enzymes must have complementary shapes + + \subsubsection*{Indicued fit model} + + Active site may change to fit subtrate + + \subsection*{Coenzymes} + + "Helper" molecules to enzymes. Non-protein molecules. Temporarily forms a loose bond with protein molecule to form active enzyme. Coenzymes are not specific to the substrate (different to enzymes). + + \section*{Digestion of protein} + + Proteins are hydrolysed by the \textit{pepsin} enzyme (\(\implies\) addition of \ce{H2O}). + + \begin{description} + \item [Hydrolysis:] breaking of strong covalent (peptide) bonds + \item [Denaturation:] breaking of weak bonds (dispersion, H-bonds) + \end{description} + + \section{Carbohydrates} \subsubsection*{Monosaccharides} -- 2.47.1