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z_0yK~U)w$~Q?)CV1y2q->W3CWi27bZw2^C)DnGc$=*C*E( zz;0IhO@A&p_5Zd&@! zaDjOZ9&J^gDm`_%_j;p6H-9hvvkOS{|IL1a_kR>nZ8dWXIA&RUGjk6TJr)uU76UkD zb!#v4uRAzqEfPIe5_S^SuQ@db2Nx1{?yvXN{xP?3AYuP!bMntXf<#Y1LY!SxLV}%F zl7o$xheLveTZ~PNlUtNaltqG-M?y+mh~$4a`C3K6+}_f~iiDMo^*@XD|3NvBaI6in zPXz;V)_anh>sRb*8VsA$Nw6DDK)?oC=L|F{DWnSMQpbT+(9a@&s&BaWB!Qx--&Jk2 zdkLCrLl7CxP4TypoKD0+DG`id$mxZL1)7;?znd8NtEN2oNGvW@#$@W|>S>skIxHYO pKJGHT-D^UpG$Vxl&*VD07(2OmIDMs)n~RNu6ONKnQdtV_KLCmX4N3q2 literal 0 HcmV?d00001 diff --git a/chem/organic-reactions.tex b/chem/organic-reactions.tex new file mode 100644 index 0000000..df0ae52 --- /dev/null +++ b/chem/organic-reactions.tex @@ -0,0 +1,76 @@ +\documentclass[a4paper]{article} +\usepackage[dvipsnames, table]{xcolor} +\usepackage{amsmath} +\usepackage{amssymb} +\usepackage{chemfig} +\usepackage[a4paper,margin=2cm]{geometry} +\usepackage{mhchem} +\usepackage{tabularx} +\usepackage{tcolorbox} +\usepackage{wrapfig} + +\title{Organic Reactions} +\author{Andrew Lorimer} +\date{} + +\newcolumntype{L}[1]{>{\hsize=#1\hsize\raggedright\arraybackslash}X}% +\newcolumntype{R}[1]{>{\hsize=#1\hsize\raggedleft\arraybackslash}X}% +\definecolor{important}{HTML}{fc9871} +\newtcolorbox{warning}{colback=white!90!black, leftrule=3mm, colframe=important, coltext=important, fontupper=\sffamily\bfseries} + +\begin{document} + +\maketitle + +\subsubsection*{Alkanes} + +\begin{itemize} + \item Combustion (oxidation) + \item Substitution + \begin{itemize} + \item alcohol from haloalkane + \item UV catalyst + \end{itemize} +\end{itemize} + +\subsubsection*{Alkenes} + +\begin{itemize} + \item Combustion (oxidation) + \item Addition + \item Addition polymerisation +\end{itemize} + +\subsubsection*{Alcohols} + +\begin{itemize} + \item Oxidation / combustion: + \begin{itemize} + \item primary alcohol \ce{->[{[O]}]} aldehyde \ce{->[{[O]}]} carboxylic acid + \item secondary alcohol \ce{->[{[O]}]} ketone + \item Catalysts: \ce{H+/MnO4- (aq)} or \ce{H+/Cr2O7{2-} (aq)} + \end{itemize} + \item Esterification with carboxylic acids (condensation) +\end{itemize} + +\subsubsection*{Carboxylic acids} + +\begin{itemize} + \item Acid/base reactions: + \begin{itemize} + \item With \ce{-NH2}: \ce{carboxylic acid + amine -> ammonium salt ->[heat][dehydration] amide + H2O} + \item With \ce{H2O}: \ce{RCOOH + H2O <=> RCOO- + H2O-} + \end{itemize} + \item Esterification with alcohols (condensation): \\ + \-\hspace{1em}\ce{carboxylic acid + alcohol -> ester + H2O} +\end{itemize} + +\subsubsection*{Esters} + +\begin{itemize} + \item Hydrolysis (reverse of esterification): \\ + \-\hspace{1em}\ce{ester + water ->[catalyst] carboxylic acid + alcohol} + \item Polyesters +\end{itemize} + +\end{document} -- 2.47.1