From d7d5be9aa432f163c9fc958491b3d57f7763571d Mon Sep 17 00:00:00 2001 From: Andrew Lorimer Date: Mon, 4 Mar 2019 11:20:43 +1100 Subject: [PATCH] [chem] primary cells and fuel cells --- chem/electrochemistry.md | 22 +++++++++++++++++++--- 1 file changed, 19 insertions(+), 3 deletions(-) diff --git a/chem/electrochemistry.md b/chem/electrochemistry.md index 20de01e..e439add 100644 --- a/chem/electrochemistry.md +++ b/chem/electrochemistry.md @@ -60,7 +60,23 @@ Usually one member of pair is used as electrode (except for *inert electrodes*, 2. Higher equation will proceed left to right 3. Lower equation will proceed right to left -emf for each cell is calculated as $E^0(\text{red}) - E^0(\text{ox})$ -Then total emf is $\sum_{i=1}^2 \Sigma E^0({i})$ +emf for each cell is calculated as $E^0(\text{red}) - E^0(\text{ox})$ + +For a *spontaneous* (primary/fuel cell) reaction to occur, species on left must be in electrical contact with species on lower right + +### Primary cells + +Used for low-current electronic devices. Fixed quantity of reactants. + +- **Zinc-carbon dry cell** - carbon rod cathode and zinc anode (case) in ammonium chloride/zinc chloride electrolyte +- **Alkaline cell** - steel cathode (case) and steel/brass rod anode in potassium hydroxide electrolyte +- **Silver-zinc cell** - zinc anode, graphite/silver-oxide electrolyte, potassium hydroxide electrolyte +- **Lithium cell** - magnesium oxide anode, nickel/steel cathode (case), lithium, electrolyte. Lithium is low on electrochemical series enables higher voltage + +### Fuel cells + +Used for vehicles/long-lasting applications. ce{H2} may be replenished. + +- **Alkaline fuel cell** - ce{KOH(aq)} electrolyte, ce{H2(g)} from tank, ce{O2(g)} from atmosphere, water out of hydrogen side +- **Acid fuel cell** - ce{H3PO4} electrolyte, water out of oxygen side -For a spontaneous reaction to occur, species on left must be in electrical contact with species on lower right \ No newline at end of file -- 2.43.2